Oxidative Desulfurization of Diesel from the Topping Plant using 1-Butyl-3-Methylimidazolium Hydrogen Sulfate [Bmim][HSO4] as Catalyst

Convenient method for the synthesis of symmetrical disulfides using 1-butyl- 3-methylimidazolium hydroxide in water

Synthesis, Characterization and Application of 1-Butyl-3 Methylimidazolium Chloride as Green Material for Extractive Desulfurization of Liquid Fuel

The possible application of imidazolium ionic liquids as energy-efficient green material for extractive deep desulfurization of liquid fuel has been investigated. 1-Butyl-3-methylimidazolium chloride [BMIM]Cl was synthesized by nucleophilic substitution reaction of n-methylimidazolium and 1-chlorobutane. Molecular structures of the ILs were confirmed by FTIR, (1)H-NMR, and (13)C-NMR. The therma...

Oxidative desulfurization of light fuel oil by using hydrogen peroxide in the presence of acetic acid catalyst

Hydrogen peroxide as an oxidant agent was used for desulfurization of a petroleum hydrocarbon fraction (C10-C22) with boiling range of 175-375 ℃, (light fuel oil) in the presence of acetic acid as catalyst. The oxidation was performed in an ultrasonic bath. It is found that increasing the amount of hydrogen peroxide lead to increase the oxidation rate and so desulfurizatio...

An efficient method for the preparation of symmetrical disulfides using 1-butyl- 3-methylimidazolium hydroxide in aqueous medium

In this study, a one-pot and efficient method is reported for the synthesis of symmetrical disulfides from alkyl halides in the present of sulfur and 1-butyl-3-methylimidazolium hydroxide as a basic reagent and phase transfer catalyst. The reaction proceeded very fast and afforded the desired products in moderate to excellent isolated yields.

Reduction of carbon dioxide in 1-butyl-3-methylimidazolium acetate.

Gaseous CO(2) is almost irreversibly absorbed by the room temperature ionic liquid 1-butyl-3-methylimidazolium acetate ([C(4)mim][Ac]) in which it undergoes a chemically irreversible, one electron electrochemical reduction, suggesting a means for the sequestration of the greenhouse gas.